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Exposing the fakers, forgers and fraudsters


London Regional Group: The detection of fraud in paintings, Belgrave Square, London


Botticelli detail With paintings such as Rubens’ Massacre of the Innocents going under the hammer for nearly GB£50m a couple of years ago, there is every incentive to fake a masterpiece.

But how to spot the forgery from the genuine article requires a complex range of skills, ranging from relatively simple detective work to some highly developed chemical analysis. SCI’s London Regional Group was treated to a fascinating talk on the subject by Dr Nicholas Eastaugh, a scientific consultant specialising in art, on 18 January 2005.

In his talk, ‘The detection of fraud in paintings’, Dr Eastaugh explained that a painting is composed of a support (such as a canvas or wooden board), a layer of preparation, a preparatory drawing, a series of paint layers, and a varnish. One or more of these components can be tampered with, but there are some definite giveaways. A painting based on an old wooden board, for example, does not necessarily indicate authenticity; someone may have just painted on an old board.

Pigments are ‘information rich’ — there are often many of them in a painting, and each has many variations, including the raw material source or method of manufacture. Dr Eastaugh focused on their analysis for most of his talk.

Ultramarine, made from lapis lazuli, is used as a dating pigment, because natural ultramarine was no longer used after a certain date. The pigment was prohibitively expensive in Renaissance times, due to its long journey from Afghanistan, and so was used very sparingly, often just for the Madonna’s robe. Renaissance artists even had a special provision for purchasing ultramarine written into their contracts, along with the gold leaf.

All that changed in the 1820s when a competition was launched in France to find an artificial substitute, so any supposedly Renaissance painting which contains the substitute is a fake. A forger who got wise to this, and used authentic ultramarine to fake an old painting, might be surprised to find himself caught out after all. Modern lapis is sourced in Russia and South America.

pigmentsSome substances lend themselves well to this kind of geological sourcing. It is possible to characterise the isotopes and trace elements of lead in lead-based pigments, the sulphur in ultramarine, or examine the general composition of iron-based earth pigments.

Dr Eastaugh discussed some of the methods used for obtaining pigment samples. If a cross-section is needed to look at paint layers, a sample of pigment needs to be physically removed from a painting. Where possible, this is taken from the very edge of the painting, under the frame. Fortunately there is quite a collection of samples previously taken from paintings, including many in London’s National Gallery, so these samples can be reused as new techniques develop.

Current methods of analysis include polarised light microscopy, elemental analysis by X-ray spectrometry and structural characterisation with X-ray diffraction. Increasing use is being made of newer techniques such as Raman microscopy, which uses a laser beam to interact with the molecules in the material and scatter some of the light.

The success of analysing pigments depends on information about the materials being both up to date and widely available. Together with some colleagues, Dr Eastaugh has set up the Pigmentation Project to do just that. To date the project has published a two-volume Pigment compendium and has set up a database, Lazurite, which features sample analysis, images and information on sampling sites. The project can be viewed online here at www.pigmentum.org.

by Joanna Pegum
Web Editor