2019 has been declared by UNESCO as the Year of the Periodic Table. To celebrate, we are releasing a series of blogs about our favourite elements and their importance to the chemical industry. Today’s blog focuses on lead and its place in the battery industry.
2019 is a critical year for the European Battery Industry. As policymakers set priorities to decarbonise the energy systems, whilst boosting Europe’s economic and technical performance, lead-acid batteries have become a viable player in the battery industry.
Increased government action and ongoing transformations to address the environmental situation has furthered global interest in the lead battery market, as they remain crucial in the battle to fight against the adverse effects of climate change. Subsequently, reliance on fuel technologies is lessening as we see a rise in the lead battery industry which had a market share of 31% in year 2018 with an annual growth rate of 5.4%.
According to reports by Reports and Data, the Global Lead- Acid Battery market is predicted to reach USD 95.32 Billion by 2026. Rising demand for electric vehicles and significant increases of this battery use in sectors including automotive, healthcare, and power industries, are a large push behind the growth in this market.
Thus, expansion of these sectors and particularly the automobile sector, means further development in this market will be underway, especially as it is the only battery technology to meet the technical requirements for energy storage on a large market scale.
Lead-acid battery is a rechargeable cell, comprising plates of lead and lead oxide, mixed in a sulfuric acid solution, which converts chemical energy into electrical power. The oxide component in the sulfuric acid oxidizes the lead which in turn generates electric current.
In the past, lead has fallen behind competing technologies, such as lithium-ion batteries which captured approximately 90% of the battery market. Although lithium-ion batteries are a strong opponent, lead still has advantages. Lead batteries do not have same fire risks as lithium-ion batteries and they are the most efficiently recycled commodity metal, with over 99% of lead batteries being collected and recycled in Europe and U.S.
Researchers are trying to better understand how to improve lead battery performance. A build-up of sulfation can limit lead battery performance by half its potential, and by fixing this issue, unused potential would offer even lower cost recyclable batteries. Once the chemical interactions inside the batteries are better understood, one can start to consider how to extend battery life.
A 3D battery made using self-assembling polymers could allow devices like laptops and mobile phones to be charged much more rapidly.
Usually in an electronic device, the anode and cathode are on either side of a non-conducting separator. But a new battery design by Cornell University researchers in the US intertwines the components in a 3D spiral structure, with thousands of nanoscale pores filled with the elements necessary for energy storage and delivery.
This type of ‘bottom-up’ self-assembly is attractive because it overcomes many of the existing limitations in 3D nanofabrication, enabling the rapid production of nanostructures at large scales.
In the Cornell design, the battery’s anode is made of gyroidal (spiral) thin films of carbon, generated by block copolymer self-assembly. They feature thousands of periodic pores around 40nm wide. The pores are coated with a 10 nm-thick separator layer, which is electronically insulating but ion-conducting. Some pores are filled with sulfur, which acts as the cathode and accepts electrons but doesn’t conduct electricity.
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‘This is potentially ground-breaking, if the process can be scaled up and the quality of the electrodes can be ensured,’ comments Yury Gogotsi, director of A.J. Drexel Nanomaterials Institute, Philadelphia, US. ‘But this is still an early-stage development, proof of concept. The main challenge is to ensure that no short-circuits occur in the structure.
In July 2017, the UK government announced plans to end the sale of all new petrol and diesel cars and vans by 2040, but there’s a long way for the electric vehicle market to go before that target can be reached – low-emission vehicle sales still account for just 0.5% of total car sales.
Last week, the European Commission announced a new Innovation Deal that could go some way to overcoming barriers to electric vehicle development and acceptance by consumers.
Entitled ‘From e-mobility to recycling: the vitreous loop of the electric vehicle’, it is designed to help innovators address regulatory obstacles to the recycling and re-use of propulsion batteries in second-life applications, such as energy storage.
The deal comprises a multi-disciplinary working group of partners across industry and government in France and the Netherlands. In France, Renault, Bouygues and the Ministries for the Ecological and Inclusive Transition and Economy and Finance; in the Netherlands, renewable energy technology company LomboXnet, the Provice of Utrecht, and the Ministries of Infrastructure and Water Management, Economic Affairs, and Climate Policy.
Carlos Moedas, EU Commissioner for Research, Science and Innovation, said, ‘The electric vehicle revolution is a testimony to how innovation generates growth and fundamentally changes society for the better. In order for Europe to stay in the lead of this innovation race, we need to work together with innovators and authorities to make sure our laws do not hamper innovation. This Innovation Deal will clarify the regulatory landscape in this area, and boost demand for electric vehicles.’
Robin Berg, founder of LomboXnet is one such innovator set on fundamentally changing society for the better. In Utrecht, the Netherlands, his company has set up a smart solar charging network that allows excess solar power harvested via rooftop photovoltaic panels to be stored in electric vehicle batteries – the energy can then be transferred between car and home as demand requires.
‘Enhancing the economic value of car batteries through vehicle-to-grid applications, second-life battery projects and smart solar charging of cars, creates huge business opportunities,’ Berg said.
‘The Smart Solar Charging consortium in Utrecht Region led by LomboXnet together with Renault seeks to increase these opportunities to spur the transition to a renewable energy system and a zero-emission mobility future. Europe is leading in these developments; this Innovation Deal offers a chance to further strengthen Europe’s leadership.’
Pure electric vehicle sales were down in the first two months of 2018 compared with the previous year – although sales of plug-in hybrid cars, which combine a conventional petrol or diesel engine with an electric motor that can be charged at an outlet or on the move, were up by 40% over the same period.